The Chinese duo scored 77.50 points despite an error on their throw triple flip when Sui put her hand down on the landing.
They're seeking to end China's 10-year wait for a pairs gold at the finals after Chinese pairs won silver in each of the past three seasons. Sui and Han are being chased by three Russian pairs, with Alexandra Boikova and Dmitry Kozlovsky in second on 76.65. Third are Daria Pavliuchenko and Denis Khodykin, with Anastasia Mishina and Alexander Galliamov fourth.
It was a disappointing showing for Canada's Kirsten Moore-Towers and Michael Marinaro, who placed sixth and last after Moore-Towers fell on the landing of a throw triple loop and Marinaro stepped out of a triple toeloop.
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